Try out with sites like shrekhan.com, kotaksecurities.com or 5paisa.com.
Also make sure you understand how the market works through economic times paper or watch a lot of CNBC TV.
Invest in beginning only that much you can afford to loose.
It's much better to learn while doing it. Just register to a legitimate trading site, and invest a bit first, and make some practices to trade there. You'll find practicing is more meaningful instead of reading trading e-book first.