what is the properties of tacn

Coordination chemistry TACN is a popular tridentate ligand. It is three-fold symmetric and binds to one face of an octahedron of metalloids and transition metals. The (TACN)M unit is kinetically inert, allowing further synthetic transformations on the other coordination sites. [edit] Illustrative complexes Although TACN characteristically coordinates to metals in mid- and high oxidation states, e.g. Ni(III), Mn(IV), Mo(III), W(III), exceptions occur. To illustrate, 1,4,7-triazacyclononane reacts readily with Mo(CO)6 and W(CO)6 to produce the respective air-stable tricarbonyl compounds, [(?3 -TACN)Mo(CO)3] and [(?3-TACN)W(CO)3]. Both have an oxidation state of zero. After further reacting with 30% H2O2, the products are [(?3-TACN)MoO3] and [(?3-TACN)WO3]. Both of these oxo complexes have an oxidation state of 6. The macrocyclic ligand does dissociate in the course of this dramatic change in formal oxidation state of the metal. The complex, [?3-TACN)Cu(II)Cl2], a catalyst for hydrolytic cleavage of phosphodiester bonds in DNA.[3] is prepared as follows from TACN trihydrochloride: TACN.3HCl + CuCl2.3H2O + 3NaOH ? [(?3-TACN)CuCl2] + 6H2O + 3NaCl Mn-TACN complexes catalyze epoxidation of alkenes such as styrene using H2O2 as an oxidant in a carbonate buffered methanol solution at a pH of 8.0. These reagents are considered environmentally benign,[4] [(?3-TACN)Mn] + H2O2 + NaHCO3 + (C6H5)C2H3 ? [(?3-TACN)Mn] + 2H2O + CO2 + (C6H5)C2H2O Chromium (III) sources, e.g. generated by heating CrCl3.6H2O in DMSO react with TACN to form both 1:1 Cr:and 2:1 complexes,[5] e.g. yellow [(TACN)2Cr]3+.[6]

Synthesis The ligand is prepared from diethylene triamine as follows by macrocyclization using ethyleneglycol ditosylate. H2NCH2CH2NHCH2CH2NH2 + 3 TsCl ? Ts(H)NCH2CH2N(Ts)CH2CHH2N(H)Ts + 3 HCl Ts(H)NCH2CH2N(Ts)CH2CH2N(H)Ts + 2 NaOEt ? Ts(Na)NCH2CH2N(Ts)CH2CH2N(Na)Ts Ts(Na)NCHH2CH2N(Ts)CH2CH2N(Na)Ts + TsOCH2CH2OTs + ? [(CH2CH2N(Ts)]3 + 2 NaOTs [(CH2CH2N(Ts)]3 + 3 H2O ? [CH2CH2NH]3 + 3 HOTs

1,4,7-Triazacyclononane, known as "TACN" which is pronounced "tack-en," is a cyclic organic compound with the formula C6H12(NH)3. TACN is derived, formally speaking, from cyclononane by replacing three equidistant CH2 groups with NH groups. TACN is one of the oligomers derived from aziridine, C2H4NH. Other members of the series include diazacyclohexane, C4H8(NH)2, and the cyclic tetramer 1,4,7,10-tetraazacyclododecane.