OK you downloading CD burning buffs, I need your help.

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First of all, I installed finalburner which is a free CD burner. I found a site that I could download free music. I have W9indows 2000. I opened up the media player to find that comes with roxio. So I downloaded a song, hit "copy to CD. the first time it didn't work but the second time it did. This was the first time I found out you don't have to listen to the whole track to burn it. So there. I had one song. On one CD. I went to Kmart and bought a 5 pack of blank CDs. After messing around, I got an album I had downloaded on a CD, plus two other songs that I really didn't mean to put on there but that's OK. I also got one more song on another CD. So about those twoCDs with one song. can I put that cD back in and have it start after the one song? I ask this because I got a message at one point, don't start burning another CD until you're finished with this one. Also on finalburner I noticed CD ripping. What is that? It sounds like erasing. By the way, one other thing. With cassette, there are standard for voice and there are high bias CRo2 which was sounded better and cost more. At Kmart I noticed 5 packs for 1.99, 2.99 and even 5.99. Theyt were all the same length, everything was the same. Is there any difference on blank CD? My guess is no. I bought the 5 pack for 1.99.