What you need to know in designing a good website with great looks?

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What I can say is that the most attrative the website with good creative look the most people will again come and see what's inside. Isn't it. So what we need to create a good looking website. What I think for designing a website photoshop instrustions are needed to learn and design a good looking website. But I don't know which version of abobe photoshop. there are many like CS5, lightroom and others. Can someone expalin me about all this stuff, means whats its like to have lightroom or cs5/6 or other tools from adobe. By the way I never checked for my spellings while typing, so if you feel it annoying that some words are incorrect then avoid them and just focus on my needs.