Chemistry HELP! Redox Reaction :|

@jeeyah (1092)
Philippines
August 11, 2010 9:26am CST
Hi, I have a Chemistry HW and I need some help. How do I balance the following redox reaction in basic solution? MnO4(2-)(aq) - MnO2(s) + MnO4(-)(aq) Can anyone please help me? Also, how do we compare/arrange the reducing/oxidizing properties of elements? I need this immediately. :( Thanks so much to those who will share their knowledge with me! :)
2 responses
• China
11 Aug 10
Hi,jeeyah.3MoO4(2-)(aq)+4H(+)=MnO2(s)+2MnO4(-)(aq)+2H2O or 3Mn04(2-)+2H2O=2MnO4(-)+MnO2+4OH(-).It depends on the Ph of the solution.To balance it,you should find out which element's chemical valence change.We can see Mn change in this redox reaction.Then you can write down each different valences and make sure the up valence and the down change the same numbers.Maybe it's difficult because we should understand the Ph which leads to different answers.That is my opinion and welcome to discuss.Wish it can help you:)
@fpsninja (874)
12 Aug 10
Its been a long while since i did these, but how do u do them agian? I remember something like finding the difference in charge between the 2 sides after balancing the equation. THen balancing the charge using H+ ions. THen use water to balance the H+ ions. Then finally add O2 to balance the O2 atoms. Was it something like that?
@fpsninja (874)
12 Aug 10
wait, now i remember, you have to seperate out the equation into the two parts. So MnO4 2- MnO2. First you balance out there oxygens using H2O So MnO4 2- MnO2 + 2H2O Then u add H+ to the other side of H2O to balance out hydrogen so: MnO4 2- + 4 H+ MnO2 + 2H20 Then u balance electron to make both sides equal, so u need to add 2 electrons to right hand side so: MnO4 2- + 4 H+ + 2 electons MnO2 + 2H2O (this is the first equation) Then for MnO4 2- MnO4 - you need to just add an electron to rhs (right hand side) to balance so: MnO4 2- MnO4- + e- Then you just balance electrons, so u need to double the second equation to make it 2 e- to balance the 2e- in the first equation. Making it: 3MnO4 2- + 4H+ 2MnO4 - + MnO2 add 2 H2O Aha, now i remeber! Hope this helps!
@p3ks626 (6538)
• Philippines
12 Aug 10
Oh my gosh! I remember i had the same problems before. I am so glad I graduated already and I dont need to solve redox equations anymore. whew! Sorry I cant help you with that problem. I used to make friends with my classmates who were good in chemistry before so i can just copy their work and explain things to me.